Theoretical insights into photochemical reactions initiated with circularly polarized light | Zendy

Pagni Richard M. | Zendy; Bartmess John | Zendy

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Theoretical insights into photochemical reactions initiated with circularly polarized light

Author(s) -

Pagni Richard M.,

Bartmess John

Publication year - 2006

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.20275

Subject(s) - chemistry , chirality (physics) , circular polarization , enantiomer , photochemistry , enantiomeric excess , stereochemistry , optics , enantioselective synthesis , organic chemistry , catalysis , quantum mechanics , physics , chiral symmetry breaking , nambu–jona lasinio model , quark , microstrip

A theoretical analysis of several hypothetical photoreactions initiated with circularly polarized light has been carried out to determine the factors influencing the enantiomeric excess of recovered reactant. The anistropic g value is the dominant influence, although quantum yields and F values may be important in certain cases. Chirality, 2006. © 2006 Wiley‐Liss, Inc.

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