Premium
Asymmetric epoxidation of cinnamyl alcohol with optically active titanium complexes
Author(s) -
Pérez Yolanda,
MoranteZarcero Sonia,
del Hierro Isabel,
Sierra Isabel,
Fajardo Mariano,
Otero Antonio
Publication year - 2005
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.20217
Subject(s) - chemistry , cinnamyl alcohol , menthol , stereoselectivity , alcohol , borneol , chirality (physics) , titanium , catalysis , asymmetric induction , organic chemistry , enantioselective synthesis , benzaldehyde , medicinal chemistry , stereochemistry , cinnamaldehyde , medicine , chiral symmetry breaking , alternative medicine , physics , traditional chinese medicine , pathology , quantum mechanics , nambu–jona lasinio model , quark
A family of titanium(IV) alkoxo compounds [{Ti(O‐ i ‐Pr) 2 (OR) 2 } 2 ] 1–4 prepared by alcohol exchange of Ti(O‐ i ‐Pr) 4 and a chiral higher‐boiling alcohol [ROH = 1,2:3,4‐di‐ O ‐isopropylidene‐α‐ d ‐galactopyranose, 1,2:5,6‐di‐ O ‐isopropylidene‐α‐ d ‐glucofuranose, (1 R ,2 S ,5 R )‐(−)‐menthol, (1 S ‐ endo )‐(−)‐borneol, (1 S ,2 R ,5 S )‐(+)‐menthol, and (+)‐borneol] has been tested to evaluate their catalytic activity and stereoselectivity in the asymmetric epoxidation of cinnamyl alcohol. © 2005 Wiley‐Liss, Inc. Chirality
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom