Photoreaction of a racemate proceeding through radical or ion pairs. The effect of circularly polarized light on the enantiomeric excess of recovered reactant | Zendy

Pagni Richard M. | Zendy; Bartmess John | Zendy

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Photoreaction of a racemate proceeding through radical or ion pairs. The effect of circularly polarized light on the enantiomeric excess of recovered reactant

Author(s) -

Pagni Richard M.,

Bartmess John

Publication year - 2003

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.10289

Subject(s) - chemistry , enantiomer , enantiomeric excess , substrate (aquarium) , ion , photochemistry , stereochemistry , organic chemistry , enantioselective synthesis , catalysis , oceanography , geology

A simple theory has been developed to explain how circularly polarized light will affect the outcome of a photoreaction of a racemic substrate proceeding through ion pairs or radical pairs. One can calculate the enantiomeric excess and amount of recovered substrate at any stage of the reaction. Chirality 15:772‐776, 2003. © 2003 Wiley‐Liss, Inc.

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