Synthesis of novel chiral Cu or Ag/S,N cluster complexes and absolute stereostructures as determined by x‐ray crystallography | Zendy

Shi Min | Zendy; Jiang JianKang | Zendy

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Synthesis of novel chiral Cu or Ag/S,N cluster complexes and absolute stereostructures as determined by x‐ray crystallography

Author(s) -

Shi Min,

Jiang JianKang

Publication year - 2003

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.10251

Subject(s) - chemistry , thiazolidine , cluster (spacecraft) , crystallography , copper , ligand (biochemistry) , dichloromethane , metal , crystal structure , x ray , stereochemistry , organic chemistry , biochemistry , physics , receptor , quantum mechanics , solvent , computer science , programming language

Novel chiral copper(I) and silver(I) metal complexes were synthesized from the reaction of chiral 1,3‐thiazolidine‐2‐thione ligand with CuCl and AgOAc in dichloromethane in the presence of Et 3 N and DMAP at room temperature. Their unique crystal structures were determined by X‐ray analysis. Four Cu(I) atoms and four 1,3‐thiazolidine‐2‐thione ligands form a butterfly‐type metal cluster. Six Ag(I) atoms and six 1,3‐thiazolidine‐2‐thione ligands form another butterfly‐type cluster. Chirality 15:605–608, 2003. © 2003 Wiley‐Liss, Inc.

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