Deracemization of an axially chiral biphenylic derivative as a tool for investigating chiral recognition in self‐assemblies | Zendy

Borocci Stefano | Zendy; Ceccacci Francesca | Zendy; Galantini Luciano | Zendy; Mancini Giovanna | Zendy; Monti Donato | Zendy; Scipioni Anita | Zendy; Venanzi Mariano | Zendy

Premium

Deracemization of an axially chiral biphenylic derivative as a tool for investigating chiral recognition in self‐assemblies

Author(s) -

Borocci Stefano,

Ceccacci Francesca,

Galantini Luciano,

Mancini Giovanna,

Monti Donato,

Scipioni Anita,

Venanzi Mariano

Publication year - 2003

Publication title -

chirality

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.43

H-Index - 77

eISSN - 1520-636X

pISSN - 0899-0042

DOI - 10.1002/chir.10230

Subject(s) - chemistry , axial symmetry , chirality (physics) , derivative (finance) , computational chemistry , combinatorial chemistry , nanotechnology , stereochemistry , chiral symmetry breaking , quantum mechanics , symmetry breaking , physics , financial economics , nambu–jona lasinio model , economics , materials science

Two diastereomeric cationic surfactants derived from L ‐proline, in which the second chiral center is a quaternary nitrogen, have been separated and fully characterized. The recognition properties of the aggregates formed by the two diastereomeric surfactants have been investigated by circular dichroism and 1 H NMR through deracemization of racemic 2‐carboxy‐2′‐dodecyloxy‐6‐nitrobiphenyl. Chirality 15:441–447, 2003. © 2003 Wiley‐Liss, Inc.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research