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Ligand‐accelerated cadmium‐catalyzed asymmetric allylation reactions in aqueous media
Author(s) -
Kobayashi Shū,
Aoyama Naohiro,
Manabe Kei
Publication year - 2002
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10154
Subject(s) - chemistry , aqueous medium , catalysis , ligand (biochemistry) , bromide , diamine , aqueous solution , enantioselective synthesis , cadmium , chiral ligand , combinatorial chemistry , organic chemistry , biochemistry , receptor
Catalytic asymmetric allylation of aldehydes with allyltributyltin in aqueous media has been realized using combinations of cadmium bromide and chiral diamine ligands. These ligands were found to accelerate the reactions significantly. Chirality 15:124–126, 2003. © 2003 Wiley‐Liss, Inc.