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Exo ‐selective asymmetric diels‐alder reaction of acrylate ester
Author(s) -
Kawamura Masato,
Kudo Kazuaki
Publication year - 2002
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10130
Subject(s) - chemistry , cyclopentadiene , selectivity , diels–alder reaction , acrylate , chloride , methyl acrylate , organic chemistry , medicinal chemistry , catalysis , polymer , copolymer
Diels‐Alder reaction of 2‐acryloyloxy‐2′‐(2‐pyridylazo)‐1,1′‐binaphthyl with cyclopentadiene in the presence of an equimolar amount of tin(IV) chloride showed unusual exo ‐selectivity with a high degree of diastereofacial differentiation. Chirality 14:727–730, 2002. © 2002 Wiley‐Liss, Inc.