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Enantiomeric recognition of amino acids using a chiral spiropyran derivative
Author(s) -
Tsubaki Kazunori,
Mukoyoshi Koichiro,
Morikawa Hiroshi,
Kinoshita Takayoshi,
Fuji Kaoru
Publication year - 2002
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10111
Subject(s) - spiropyran , chemistry , merocyanine , enantiomer , amino acid , moiety , derivative (finance) , stereochemistry , optically active , chirality (physics) , ionone , organic chemistry , photochromism , chiral symmetry breaking , biochemistry , physics , quantum mechanics , nambu–jona lasinio model , financial economics , economics , quark
An optically active spiropyran 1 with a binaphthol moiety as a chiral source was synthesized. The colored merocyanine form of ( R )‐ 1 obtained by the UV irradiation remained in the presence of D ‐amino acids longer than with L ‐amino acids. Chirality 14:713–715, 2002. © 2002 Wiley‐Liss, Inc.