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Synthesis and structure of poly(binaphthyl salen manganese complex) and its application to asymmetric epoxidation
Author(s) -
Maeda Takeshi,
Furusho Yoshio,
Takata Toshikazu
Publication year - 2002
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10093
Subject(s) - chemistry , manganese , metal salen complexes , catalysis , derivative (finance) , polymer chemistry , stereochemistry , medicinal chemistry , organic chemistry , financial economics , economics
Poly(binaphthyl salen manganese complex)es 3 ‐Mn were synthesized from a 3,3′‐diformylbinaphthol derivative, α,ω‐diamines, and Mn(OAc) 2 . Their helical structures were well‐supported by their IR, UV, and CD spectra. The catalysis of 3 ‐Mn in an asymmetric epoxidation was investigated. Chirality 14:587–590, 2002. © 2002 Wiley‐Liss, Inc.
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