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Overall view of the use of chiral platinum(II) complexes as chiral derivatizing agents (CDAs) for the enantiodiscrimination of unsaturated compounds by 195 Pt NMR
Author(s) -
UccelloBarretta Gloria,
Bernardini Raffaella,
Balzano Federica,
Salvadori Piero
Publication year - 2002
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10073
Subject(s) - chemistry , platinum , ethylene , chiral derivatizing agent , covalent bond , organic chemistry , stereochemistry , enantiomer , catalysis , chiral column chromatography
The use of organometallic CDAs based on ethene‐platinum(II) complexes, covalent cis‐ and trans‐ dichloro(Am)(ethylene)platinum(II), and ionic [PtCl 3 (C 2 H 4 )] − [AmH] + , containing primary and secondary amines, for the 195 Pt NMR enantiodiscrimination of chiral unsaturated compounds is reviewed. Chirality 14:484–489, 2002. © 2002 Wiley‐Liss, Inc.