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Optically active molecule‐based magnets: Enantioselective self‐assembling, optical, and magnetic properties
Author(s) -
Gruselle Michel,
Andres Roman,
Malezieux Bernard,
Brissard Muriel,
Train Cyrille,
Verdaguer Michel
Publication year - 2001
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10023
Subject(s) - chemistry , bimetallic strip , chirality (physics) , crystallography , enantioselective synthesis , pyridine , oxalate , molecule , bipyridine , optically active , stereochemistry , single molecule magnet , inorganic chemistry , medicinal chemistry , crystal structure , catalysis , organic chemistry , magnetization , magnetic field , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark
In this short communication we describe the synthesis and the optical and magnetic properties of optically active three dimensional (3D) bimetallic [Cr‐Mn] networks {[ΔCr III ΔMn II (ox) 3 ][ΔRu II (bpy) 3 ]ClO 4 } n 1 − Δ, {[ΛCr III ΛMn II (ox) 3 ][ΛRu II (bpy) 3 ]ClO 4 } n 1 − Λ and {[ΔCr III ΔMn II (ox) 3 ][ΔRu II (bpy) 2 p p y]} n 2 − Δ,{[ΛCr III ΛMn II (ox) 3 ][ΛRu II (bpy) 2 ppy]} n 2 − Λ (ox = oxalate, bpy = bipyridine, ppy = phenyl‐pyridine). Chirality 13:712–714, 2001. © 2001 Wiley‐Liss, Inc.