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Asymmetric addition of allyltrimethylsilane to N ‐tosylimine of (1 R )‐8‐phenylmenthyl glyoxylate
Author(s) -
Kulesza Anna,
Jurczak Janusz
Publication year - 2001
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10019
Subject(s) - chemistry , glyoxylate cycle , chirality (physics) , nucleophile , lewis acids and bases , stereochemistry , computational chemistry , medicinal chemistry , catalysis , organic chemistry , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , enzyme , quark
The addition of allyltrimethylsilane to chiral N ‐tosylimine derived from (1 R )‐8‐phenylmenthyl glyoxylate is discussed. Various Lewis acids were applied in order to postulate the stereochemical model for this type of nucleophilic addition. Chirality 13:634–635, 2001. © 2001 Wiley‐Liss, Inc.
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