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Asymmetric induction in the 1,3‐dipolar cycloaddition of chiral nitrile oxide derived from (2 R )‐bornane‐10,2‐sultam
Author(s) -
Jóźwik Julita,
Kosior Malgorzata,
Kiegiel Jaroslaw,
Jurczak Janusz
Publication year - 2001
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/chir.10017
Subject(s) - nitrile , chemistry , chirality (physics) , oxide , asymmetric induction , 1,3 dipolar cycloaddition , cycloaddition , dipole , stereochemistry , organic chemistry , enantioselective synthesis , catalysis , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark
Abstract The efficient preparation of the chiral nitrile oxide derived from N‐glyoxyloyl‐(2 R )‐bornane‐10,2‐sultam is presented. The nitrile oxide was trapped in situ with substituted olefins as dipolarophiles to furnish optically active 2‐isoxazolines. Chirality 13:629–630, 2001. © 2001 Wiley‐Liss, Inc.