Frontispiece: Isopropenyl Esters (iPEs) in Green Organic Synthesis | Zendy

Rigo Davide | Zendy; Masters Anthony F. | Zendy; Maschmeyer Thomas | Zendy; Selva Maurizio | Zendy; Fiorani Giulia | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Frontispiece: Isopropenyl Esters (iPEs) in Green Organic Synthesis

Author(s) -

Rigo Davide,

Masters Anthony F.,

Maschmeyer Thomas,

Selva Maurizio,

Fiorani Giulia

Publication year - 2022

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202284061

Subject(s) - electrophile , moiety , reactivity (psychology) , transesterification , acetone , chemistry , organic chemistry , catalysis , organic synthesis , coupling reaction , electrophilic addition , polymer chemistry , medicine , alternative medicine , pathology

Isopropenyl esters (iPEs) and isopropenyl acetate (iPAc) are characterised by a tuneable reactivity in organic synthesis. Thanks to the irreversible formation of acetone in transesterification conditions, iPEs are eco‐friendly acylating agents and can be employed for direct biomass modification and/or tandem esterification‐acetalization reactions. C−C and C−X bond formation reactions occur selectively on the isopropenyl moiety via electrophilic and/or radical additions and/or metal‐ and/or photo‐catalyzed cross‐coupling reactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research