B(C 6 F 5 ) 3 ‐Catalyzed  E ‐Selective Isomerization of Alkenes | Zendy

Kustiana Betty A. | Zendy; Elsherbeni Salma A. | Zendy; LinfordWood Thomas G. | Zendy; Melen Rebecca L. | Zendy; Grayson Matthew N. | Zendy; Morrill Louis C. | Zendy

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B(C 6 F 5 ) 3 ‐Catalyzed E ‐Selective Isomerization of Alkenes

Author(s) -

Kustiana Betty A.,

Elsherbeni Salma A.,

LinfordWood Thomas G.,

Melen Rebecca L.,

Grayson Matthew N.,

Morrill Louis C.

Publication year - 2022

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202202454

Subject(s) - isomerization , catalysis , chemistry , transition metal , reaction mechanism , computational chemistry , combinatorial chemistry , photochemistry , organic chemistry

Herein, we report the B(C 6 F 5 ) 3 ‐catalyzed E ‐selective isomerization of alkenes. The transition‐metal‐free method is applicable across a diverse array of readily accessible substrates, giving access to a broad range of synthetically useful products containing versatile stereodefined internal alkenes. The reaction mechanism was investigated by using synthetic and computational methods.

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