Front Cover: Two Rhodium(III) Ions Confined in a [18]Porphyrin Frame: 5,10,15,20‐Tetraaryl‐21,23‐Dirhodaporphyrin (Chem. Eur. J. 46/2022) | Zendy

Vetter Grzegorz | Zendy; Białońska Agata | Zendy; Krzyszowska Paulina | Zendy; Koniarz Sebastian | Zendy; PacholskaDudziak Ewa | Zendy

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Front Cover: Two Rhodium(III) Ions Confined in a [18]Porphyrin Frame: 5,10,15,20‐Tetraaryl‐21,23‐Dirhodaporphyrin (Chem. Eur. J. 46/2022)

Author(s) -

Vetter Grzegorz,

Białońska Agata,

Krzyszowska Paulina,

Koniarz Sebastian,

PacholskaDudziak Ewa

Publication year - 2022

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202202166

Subject(s) - porphyrin , rhodium , front cover , metal , metal ions in aqueous solution , ion , front (military) , chemistry , core (optical fiber) , crystallography , frame (networking) , cover (algebra) , polymer chemistry , photochemistry , materials science , catalysis , physics , organic chemistry , computer science , engineering , composite material , mechanical engineering , telecommunications , meteorology

Dwarfs are shown fixing two rhodium atoms into the skeleton of 21,23‐dirhodaporphyrin, the first [18]porphyrin to incorporate two metal atoms within its macrocyclic frame, in place of two core nitrogen donors. The 18‐π‐electron aromatic circuit is maintained, playing a crucial role in stabilizing the macrocycle, and enforcing the metal centers′ proximity. These small metal sculptures of dwarfs are a tourist attraction scattered around Wrocław, the city in Poland where the dirhodaporphyrin was synthesized. More information can be found in the Research Article by E. Pacholska‐Dudziak and co‐workers (DOI: 10.1002/chem.202201513).

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