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Front Cover: Positive Cooperativity Induced by Interstrand Interactions in Silver(I) Complexes with α,α′‐Diimine Ligands (Chem. Eur. J. 42/2022)
Author(s) -
Zare Davood,
Piguet Claude,
Prescimone Alessandro,
Housecroft Catherine E.,
Constable Edwin C.
Publication year - 2022
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202201913
Subject(s) - diimine , summit , chemistry , cooperativity , allosteric regulation , stereochemistry , front cover , cover (algebra) , crystallography , catalysis , organic chemistry , biochemistry , receptor , geography , engineering , mechanical engineering , physical geography
Because of its large size and its optimized covalency toward heterocyclic N‐donor atoms, the intermediate [Ag I L ] + unit (depicted as a paraglider) is eager to catch a second α,α’‐diimine ligands coming down from the summit of positive allosteric coperativity. The final stable [Ag I L 2 ] + complex reaches the Valley of Stability. More information can be found in the Research Article by D. Zare, C. Piguet, E. C. Constable et al. (DOI: 10.1002/chem.202200912).
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