Para ‐Fluorination of Anilides Using Electrochemically Generated Hypervalent Iodoarenes | Zendy

Berger Michael | Zendy; Lenhard Marola S. | Zendy; Waldvogel Siegfried R. | Zendy

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Para ‐Fluorination of Anilides Using Electrochemically Generated Hypervalent Iodoarenes

Author(s) -

Berger Michael,

Lenhard Marola S.,

Waldvogel Siegfried R.

Publication year - 2022

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202201029

Subject(s) - hypervalent molecule , electrochemistry , fluoride , chemistry , electrolyte , combinatorial chemistry , organic chemistry , inorganic chemistry , electrode , reagent

The para ‐selective fluorination reaction of anilides using electrochemically generated hypervalent ArIF 2 is reported, with Et 3 N ⋅ 5HF serving as fluoride source and as supporting electrolyte. This electrochemical reaction is characterized by a simple set‐up, easy scalability and affords a broad variety of fluorinated anilides from easily accessible anilides in good yields up to 86 %.

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