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Cover Feature: Structural Insights into Hysteretic Spin‐Crossover in a Set of Iron(II)‐2,6‐bis(1 H ‐Pyrazol‐1‐yl)Pyridine) Complexes (Chem. Eur. J. 6/2022)
Author(s) -
Suryadevara Nithin,
Mizuno Asato,
Spieker Lea,
Salamon Soma,
Sleziona Stephan,
Maas André,
Pollmann Erik,
Heinrich Benoît,
Schleberger Marika,
Wende Heiko,
Kuppusamy Senthil Kumar,
Ruben Mario
Publication year - 2022
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202200173
Subject(s) - bistability , spin crossover , spin states , chemistry , crystallography , condensed matter physics , materials science , physics , optoelectronics
Bistable spin‐state switching near room temperature : Two mononuclear iron(II) complexes showing technologically relevant abrupt and wide hysteretic, bistable spin‐state switching characteristics in the vicinity of room temperature are reported. The large structural reorganizations from the Jahn–Teller‐distorted high‐spin state to the less distorted low‐spin state and ethyl group conformational switching are proposed as the main contributing factors rendering the switching hysteretic. More information can be found in the Research Article by M. Schleberger, H. Wende, S. K. Kuppusamy, M. Ruben, et al. (DOI: 10.1002/chem.202103853).