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Frontispiece: Mechanistic Aspects of the Palladium‐Catalyzed Suzuki‐Miyaura Cross‐Coupling Reaction
Author(s) -
D'Alterio Massimo C.,
CasalsCruañas Èric,
Tzouras Nikolaos V.,
Talarico Giovanni,
Nolan Steven P.,
Poater Albert
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202185461
Subject(s) - palladium , catalysis , catalytic cycle , coupling reaction , coupling (piping) , field (mathematics) , chemistry , computational chemistry , materials science , organic chemistry , mathematics , metallurgy , pure mathematics
Among the different reactions that lead to the formation of C−C bonds, the Suzuki‐Miyaura approach has a fundamental role, at the level of basic research and industrial applications. In particular, the palladium is usually the metal of the corresponding catalyst. The complexity of the reaction lies in the individual steps of the cycle, as well as in the generation of the catalytically active species. Here, through a chronology from the beginnings of cross coupling, how far the field has come is analyzed. For more information, see the Review by S. P. Nolan, A. Poater et al. on page 13481.