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Frontispiece: Redox‐Neutral Tetrafluoroethylation of Aryl Alkynes with 1,1,2,2‐Tetrafluoroethane Sulfonic Acid Leading to α‐Tetrafluoroethylated Acetophenones
Author(s) -
Kawamoto Takuji,
Noguchi Kohki,
Takata Ryotaro,
Sasaki Rio,
Matsubara Hiroshi,
Kamimura Akio
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202183763
Subject(s) - sulfonic acid , aryl , redox , chemistry , medicinal chemistry , polymer chemistry , organic chemistry , alkyl
Redox‐neutral tetrafluoroethylation of aryl alkynes with 1,1,2,2‐tetrafluoroethane sulfonic acid leading to α‐tetrafluoroethylated acetophenones is described in the Full Paper by Takuji Kawamoto and co‐workers on page 9529 ff. The reaction proceeds via the formation of vinyl tetrafluoroethanesulfonates followed by a radical tetrafluoroethylation.