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Frontispiece: The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O − Hydrogen Bond of Silanol‐Silanolate Anions
Author(s) -
Weitkamp Robin F.,
Neumann Beate,
Stammler HansGeorg,
Hoge Berthold
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202180363
Subject(s) - silanol , hydrogen bond , aqueous solution , chemistry , hydroxide , hydrogen , inorganic chemistry , medicinal chemistry , crystallography , molecule , organic chemistry , catalysis
Shedding light on beautiful hydrogen bridges… of rare silanol‐silanolate anions that are constructed in the presence of weakly coordinating cations. These anions are created from siloxanes under employment of aqueous hydroxide salts and crystallize in a frosty atmosphere with cation‐dependent structural patterns. In all cases anions consisting of three SiMe 2 O‐units are predestinated. Philipp Niewöhner is acknowledged for the Frontispiece image design. For more information, see the Communication by B. Hoge et al. on page 915.