Cover Feature: Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C−S/C−N Couplings (Chem. Eur. J. 48/2021) | Zendy

Martín M. Trinidad | Zendy; Marín Mario | Zendy; Maya Celia | Zendy; Prieto Auxiliadora | Zendy; Nicasio M. Carmen | Zendy

Premium

Cover Feature: Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C−S/C−N Couplings (Chem. Eur. J. 48/2021)

Author(s) -

Martín M. Trinidad,

Marín Mario,

Maya Celia,

Prieto Auxiliadora,

Nicasio M. Carmen

Publication year - 2021

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202102641

Subject(s) - aryl , electrophile , tandem , chemistry , nucleophile , halide , nickel , combinatorial chemistry , chemoselectivity , coupling (piping) , catalysis , medicinal chemistry , polymer chemistry , organic chemistry , materials science , alkyl , metallurgy , composite material

Competent partners : π‐Allyl–nickel precatalysts supported by dialkylterphenyl phosphines efficiently couple a wide range of electrophiles including aryl iodides/bromides/chlorides and, for the first time, aryl and alkenyl tosylates with aromatic and aliphatic thiols. In addition, tandem C−S and C−N coupling of multi‐electrophile/nucleophile combinations is achieved in a completely chemoselective manner leading to highly functionalized products. More information can be found in the Full Paper by A. Prieto, M. C. Nicasio, et al. (DOI: 10.1002/chem.202101906).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research