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Cover Feature: Fine Tunable, Redox Active Octapalladium Chains Supported by Linear Tetraphosphines, Leading to Dynamically 1D Self‐Assembled Coordination Polymers (Chem. Eur. J. 47/2021)
Author(s) -
Tanase Tomoaki,
Nakamae Kanako,
Miyano Haruka,
Ura Yasuyuki,
Kitagawa Yasutaka,
Yada Shiho,
Yoshimura Tomokazu,
Nakajima Takayuki
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202102416
Subject(s) - redox , covalent bond , polymer , non covalent interactions , linear polymer , variety (cybernetics) , covalent organic framework , chemistry , frontier , nanotechnology , materials science , computer science , molecule , organic chemistry , political science , law , hydrogen bond , artificial intelligence
Dynamically 1D assembled linear Pd 8 chains with bisisocyanide linkers are shown against a backdrop of contrails lit from below by the rising sun. A variety of Pd 8 chains with a linear tetraphosphine, meso ‐dpmppm, were synthesized through both covalent and noncovalent interactions between two Pd 4 fragments. They exhibited fine‐tunable electronic states, a wide range of redox properties, and dynamic 1D self‐assembly in solution. These findings could lead to the next frontier in exploring new functions with dynamically aggregated metal building blocks. More information can be found in the Full Paper by T. Tanase et al. (DOI: 10.1002/chem.202101715).