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Slow Magnetic Relaxation in Mono‐ and Bimetallic Lanthanide Tetraimido Sulfate S(N t Bu) 4 2− Complexes
Author(s) -
Jung Jochen,
Benner Florian,
HerbstIrmer Regine,
Demir Selvan,
Stalke Dietmar
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202102289
Subject(s) - bimetallic strip , lanthanide , dysprosium , sulfate , relaxation (psychology) , magnetic relaxation , crystallography , ion , terbium , chemistry , ligand (biochemistry) , cover (algebra) , materials science , physics , inorganic chemistry , magnetic field , catalysis , magnetization , engineering , psychology , quantum mechanics , organic chemistry , social psychology , receptor , biochemistry , mechanical engineering
Invited for the cover of this issue are Selvan Demir and co‐worker from the Michigan State University at East Lansing, and Dietmar Stalke and co‐workers from the Georg‐August Universität at Göttingen. The image illustrates the first coordination of a tetraimido sulfate ligand via two of its nitrogen donors to a lanthanide ion producing mono‐ and bimetallic lanthanide complexes where specifically the dysprosium congeners, benefitting from the intrinsic oblate‐shaped electron density, feature single‐molecular magnet behavior as indicated by the observed slow magnetic relaxation. Read the full text of the article at 10.1002/chem.202101076.