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Front Cover: Slow Magnetic Relaxation in Mono‐ and Bimetallic Lanthanide Tetraimido‐Sulfate S(N t Bu) 4 2− Complexes (Chem. Eur. J. 48/2021)
Author(s) -
Jung Jochen,
Benner Florian,
HerbstIrmer Regine,
Demir Selvan,
Stalke Dietmar
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202102288
Subject(s) - lanthanide , bimetallic strip , spintronics , crystallography , chemistry , ligand (biochemistry) , magnet , molecule , relaxation (psychology) , magnetic relaxation , magnetic anisotropy , front cover , materials science , condensed matter physics , cover (algebra) , magnetic field , ferromagnetism , physics , catalysis , magnetization , quantum mechanics , organic chemistry , mechanical engineering , ion , social psychology , psychology , biochemistry , receptor , engineering
Single‐molecule magnets (SMMs) have great potential application in a range of pioneering areas, such as quantum computing, spintronics, and high‐density information storage. The properties of the molecules presented here are based on the molecular total spin and the magnetic anisotropy created by the lanthanides in a particular crystal field. An important element in SMMs’ optimization is the ligand design. Poly imido sulfur ligands are perfectly suited as the polar S + −N − ‐bond facilitates electronic and geometric adaptability to various f‐metals. Particularly the acute N–Dy–N bite angle generates advantageous magnetic properties. More information can be found in the Full Paper by S. Demir, D. Stalke et al. (DOI: 10.1002/chem.202101076).