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Humins with Efficient Electromagnetic Wave Absorption: A By‐Product of Furfural Conversion to Isopropyl Levulinate via a Tandem Catalytic Reaction in One‐Pot
Author(s) -
Ma Mingwei,
Liang Na,
Hou Pan,
Zhang Peng,
Cao Jingjie,
Liu Hui,
Xu Xingliang,
Yue Huijuan,
Tian Ge,
Feng Shouhua
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202101928
Subject(s) - furfuryl alcohol , furfural , humin , chemistry , reflection loss , catalysis , absorption (acoustics) , pyrolysis , organic chemistry , chemical engineering , materials science , composite material , fertilizer , humic acid , composite number , engineering
Both one‐pot catalytic conversion of furfural (FAL) to isopropyl levulinate (PL) and carbonization of by‐product (humins) for electromagnetic wave absorption are discussed, which provides inspiration that humins can be applied to electromagnetic wave absorption. In the former, phosphotungstic acid (PW) is employed as a homogeneous catalyst to convert FAL to PL via a tandem reaction in one pot, with the formation of a vast amount of humins. With FAL and various intermediates as substrates, it was found that humins was a polymerization product of FAL, furfuryl alcohol (FOL) and furfuryl ester (FE) with furan rings. In addition, the in situ attenuated total reflection infrared (ATR‐IR) spectra also provided a basis for the proposed reaction route. In the latter, with the humins as raw material, P species and WO 3 doped nano‐porous carbon (Humins‐700) platform formed after high‐temperature annealing is used for electromagnetic wave absorption and manifests desirable absorption performance. The minimum reflection loss (RL min ) value is −47.3 dB at 13.0 GHz with a thickness of 2.0 mm and the effective absorption bandwidth reaches 4.5 GHz (11.2–5.7 GHz).