The First Mixed Calcium Zinc Borate with a Flexible [B 8 O 17 ] Fundamental Building Block and Short UV Cutoff Edge | Zendy

Zhang Wenbin | Zendy; Guo Siru | Zendy; Han Shujuan | Zendy; Yang Zhihua | Zendy; Pan Shilie | Zendy

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The First Mixed Calcium Zinc Borate with a Flexible [B 8 O 17 ] Fundamental Building Block and Short UV Cutoff Edge

Author(s) -

Zhang Wenbin,

Guo Siru,

Han Shujuan,

Yang Zhihua,

Pan Shilie

Publication year - 2021

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202101647

Subject(s) - boron , zinc , cutoff , block (permutation group theory) , enhanced data rates for gsm evolution , calcium , ion , chemistry , materials science , crystallography , physics , mathematics , geometry , metallurgy , computer science , telecommunications , quantum mechanics , organic chemistry

The first mixed calcium zinc borate with a new fundamental building block (FBB) [B 8 O 17 ], Ca 1.13 Zn 0.87 B 8 O 14 has been successfully synthesized. It exhibits two independent interpenetrating three‐dimensional B−O anion networks constructed by [B 8 O 17 ] groups, enriching the structural diversity of B−O configurations. In particular, the UV‐Vis‐NIR diffuse‐reflectance spectrum shows that it has a short UV cutoff edge (<195 nm).

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