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The First Mixed Calcium Zinc Borate with a Flexible [B 8 O 17 ] Fundamental Building Block and Short UV Cutoff Edge
Author(s) -
Zhang Wenbin,
Guo Siru,
Han Shujuan,
Yang Zhihua,
Pan Shilie
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202101647
Subject(s) - boron , zinc , cutoff , block (permutation group theory) , enhanced data rates for gsm evolution , calcium , ion , chemistry , materials science , crystallography , physics , mathematics , geometry , metallurgy , computer science , telecommunications , quantum mechanics , organic chemistry
The first mixed calcium zinc borate with a new fundamental building block (FBB) [B 8 O 17 ], Ca 1.13 Zn 0.87 B 8 O 14 has been successfully synthesized. It exhibits two independent interpenetrating three‐dimensional B−O anion networks constructed by [B 8 O 17 ] groups, enriching the structural diversity of B−O configurations. In particular, the UV‐Vis‐NIR diffuse‐reflectance spectrum shows that it has a short UV cutoff edge (<195 nm).