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Slow Magnetic Relaxation in Mono‐ and Bimetallic Lanthanide Tetraimido‐Sulfate S(N t Bu) 4 2− Complexes
Author(s) -
Jung Jochen,
Benner Florian,
HerbstIrmer Regine,
Demir Selvan,
Stalke Dietmar
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202101076
Subject(s) - lanthanide , bimetallic strip , crystallography , magnet , relaxation (psychology) , chemistry , magnetic relaxation , germanide , single molecule magnet , ion , ligand (biochemistry) , terbium , magnetic anisotropy , molecule , spin (aerodynamics) , angular momentum , magnetic field , magnetization , metal , physics , silicon , social psychology , psychology , biochemistry , germanium , receptor , organic chemistry , quantum mechanics , thermodynamics
Abstract Lanthanide ions are particularly well‐suited for the design of single‐molecule magnets owing to their large unquenched orbital angular momentum and strong spin‐orbit coupling that gives rise to high magnetic anisotropy. Such nanoscopic bar magnets can potentially revolutionize high‐density information storage and processing technologies, if blocking temperatures can be increased substantially. Exploring non‐classical ligand scaffolds with the aim to boost the barriers to spin‐relaxation are prerequisite. Here, the synthesis, crystallographic and magnetic characterization of a series of each isomorphous mono‐ and dinuclear lanthanide (Ln=Gd, Tb, Dy, Ho, Er) complexes comprising tetraimido sulfate ligands are presented. The dinuclear Dy complex [{(thf) 2 Li(N t Bu) 2 S( t BuN) 2 DyCl 2 } 2 ⋅ ClLi(thf) 2 ] ( 1c ) shows true signatures of single‐molecule magnet behavior in the absence of a dc field. In addition, the mononuclear Dy and Tb complexes [{(thf) 2 Li(N t Bu) 2 S( t BuN) 2 LnCl 2 (thf) 2 ] ( 2b , c ) show slow magnetic relaxation under applied dc fields.