Rhamnogalacturonan II: Chemical Synthesis of a Substructure Including α‐2,3‐Linked Kdo ** | Zendy

Mancuso Enzo | Zendy; Romanò Cecilia | Zendy; Trattnig Nino | Zendy; Gritsch Philipp | Zendy; Kosma Paul | Zendy; Clausen Mads H. | Zendy

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Rhamnogalacturonan II: Chemical Synthesis of a Substructure Including α‐2,3‐Linked Kdo **

Author(s) -

Mancuso Enzo,

Romanò Cecilia,

Trattnig Nino,

Gritsch Philipp,

Kosma Paul,

Clausen Mads H.

Publication year - 2021

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202100837

Subject(s) - tetrasaccharide , glycosylation , chemistry , stereochemistry , substructure , stereoselectivity , organic chemistry , biochemistry , polysaccharide , catalysis , structural engineering , engineering

The synthesis of a fully deprotected Kdo‐containing rhamnogalacturonan II pentasaccharide is described. The strategy relies on the preparation of a suitably protected homogalacturonan tetrasaccharide backbone, through a post‐glycosylation oxidation approach, and its stereoselective glycosylation with a Kdo fluoride donor.

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