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Shape‐Adaptability and Redox‐Switching Properties of a Di‐Gold Metallotweezer
Author(s) -
Ibáñez Susana,
Peris Eduardo
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202100794
Subject(s) - redox , adduct , planar , chemistry , electrochemistry , crystallography , diimide , electron , ligand (biochemistry) , materials science , stereochemistry , receptor , molecule , electrode , inorganic chemistry , organic chemistry , computer science , biochemistry , physics , computer graphics (images) , perylene , quantum mechanics
The use of a carbazolyl‐connected di‐gold(I) metallotweezer for the encapsulation of several electron‐poor organic substrates, and a planar Au(III) complex containing a CNC pincer ligand, is described. The binding affinity of the receptor depends on the electron‐deficient character of the planar guest, with larger association constants found for the more electron‐poor guests. The X‐ray diffraction molecular structures of two host:guest adducts show that the host approaches its arms in order to facilitate the optimum interaction with the surface of the planar guests, in a clear example of an guest‐induced fit conformational arrangement. The electrochemical studies of the encapsulation of N,N’‐dimethyl‐naphthalenetetracarboxy diimide (NTCDI) show that the redox active guest is released from the receptor upon one electron reduction, thus constituting an example of redox‐switchable binding.