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In‐Situ Generated Trimetallic Molybdate Nanoflowers on Ni Foam Assisted with Microwave for Highly Enhanced Oxygen Evolution Reaction
Author(s) -
Duan Yanjie,
Huang Zhixiong,
Zhao Cheng,
Ren Jingyu,
Dong Xiangbin,
Jia Runping,
Xu Xiaowei,
Shi Shaojun
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202100278
Subject(s) - nanoflower , overpotential , molybdate , oxygen evolution , catalysis , chemical engineering , materials science , water splitting , microwave , inorganic chemistry , nanotechnology , chemistry , electrode , nanostructure , electrochemistry , metallurgy , computer science , photocatalysis , organic chemistry , telecommunications , engineering
Oxygen evolution reaction (OER) is considered as a critical half‐cell reaction of water splitting, the kinetics of which is sluggish even not favored, thus requiring highly active electrocatalysts to shrink the reaction energy barrier and improve the energy conversion efficiency. In this study, In‐situ generated trimetallic molybdate nanoflowers on Ni foam by a straightforward and time‐saving solvothermal method assisted with microwave, not only bring synergistic effect into full play between multiple metals, but also construct a well‐defined nanoflower‐like structure accompanied by larger specific area (273.3 m 2 g −1 ) and smaller size than the pristine NiMoO 4 . The resulting Ni 0.9 Al 0.1 MoO 4 ‐NF requires a relatively low overpotential of 266 mV for OER at 10 mA cm −2 , which outperforms commercial RuO 2 catalysts (274 mV). Such excellent performance compares favorably to most previously reported NiMoO 4 ‐based electrocatalysts for OER. This work not only supplies a facile method to construct a well‐defined nanoflower‐like structure on foam, but also broadens our horizons into the mechanism of OER in alkaline conditions.