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Merging Pd 0 /Pd II Redox and Pd II /Pd II Non‐redox Catalytic Cycles for the Allylarylation of Electron‐Deficient Alkenes
Author(s) -
Semba Kazuhiko,
Ohta Naoki,
Paulus Fritz,
Ohata Masaki,
Nakao Yoshiaki
Publication year - 2021
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202100075
Subject(s) - redox , catalysis , chemistry , allylic rearrangement , palladium , inorganic chemistry , organic chemistry
An allylarylation of electron‐deficient alkenes with aryl boronates and allylic carbonates has been developed. This method allows access to a wide variety of carbon skeletons from readily available starting materials. Mechanistic studies indicate that this reaction is enabled by a cooperative catalysis based on merging Pd 0 /Pd II redox and Pd II /Pd II non‐redox catalytic cycles.
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