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Frontispiece: Synthesis of Well‐Defined High‐Valent Palladium Complexes by Oxidation of Their Palladium(II) Precursors
Author(s) -
Zhang Bo,
Yan Xuechao,
Guo Shuai
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202084362
Subject(s) - hypervalent molecule , palladium , chemistry , oxidizing agent , reagent , electrophile , aryl , halide , halogen , iodine , alkyl , sulfonyl , combinatorial chemistry , organic chemistry , catalysis
Synthetic approaches to Pd III/IV complexes starting from their Pd II precursors, and the advances in this research area from early 2010 to late 2019 are presented, thereby covering oxidations exploiting various oxidizing agents including hypervalent iodine reagents, halogens, electrophilic fluorination reagents, alkyl/aryl halides, ferrocenium salts, peroxides/O 2 , sulfonyl chlorides, as well as a “greener” electrooxidation manner. Read more in the Minireview by S. Guo et al. on page 9430 ff.