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Frontispiece: Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds
Author(s) -
Bruns Jörn,
Höppe Henning A.,
Daub Michael,
Hillebrecht Harald,
Huppertz Hubert
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202083661
Subject(s) - tetrahedron , silicate , boron , sulfur , structural chemistry , crystallography , chemistry , crystal chemistry , crystal structure , stereochemistry , organic chemistry
Borosulfates are oxoanionic compounds consisting of condensed sulfur‐ and boron‐centered tetrahedra and are structurally similar to silicates. Their anionic subunits consist of alternating (SO 4 ) and (BO 4 ) tetrahedra forming oligomers, single and multiple chains, layers and extended 3D network structures. For more information on the synthesis strategies, crystal chemistry of borosulfates and their properties, see the Review by H. Huppertz et al. on page 7966 ff.