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Cover Feature: Palladium‐Catalyzed Annulation of Acyl Fluorides with Norbornene via Decarbonylation and CO Reinsertion (Chem. Eur. J. 57/2020)
Author(s) -
Sakurai Yuka,
Ogiwara Yohei,
Sakai Norio
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202003335
Subject(s) - decarbonylation , annulation , chemistry , palladium , norbornene , moiety , catalysis , cleavage (geology) , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , materials science , polymerization , composite material , fracture (geology) , polymer
Palladium‐catalyzed annulation of acyl fluorides is depicted in the cover image. Acyl fluorides are converted into the corresponding polycyclic ketones in the presence of norbornene. The reaction proceeds via C−F and ortho C−H bond cleavage of acyl fluorides and the rearrangement of the carbonyl moiety by decarbonylation and CO reinsertion. More information can be found in the Full Paper by Y. Sakurai, Y. Ogiwara, and N. Sakai on page 12972.