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Cover Feature: Enantiomerically Pure Tetravalent Neptunium Amidinates: Synthesis and Characterization (Chem. Eur. J. 41/2020)
Author(s) -
Fichter Sebastian,
Kaufmann Sebastian,
Kaden Peter,
Brunner Tobias S.,
Stumpf Thorsten,
Roesky Peter W.,
März Juliane
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202003032
Subject(s) - neptunium , halide , chemistry , metathesis , salt (chemistry) , chirality (physics) , solid state , cover (algebra) , characterization (materials science) , inorganic chemistry , polymer chemistry , medicinal chemistry , actinide , organic chemistry , materials science , nanotechnology , mechanical engineering , chiral symmetry breaking , physics , quantum mechanics , nambu–jona lasinio model , engineering , polymerization , quark , polymer
Enantiomerically pure tetravalent neptunium amidinate complexes possessing unprecedented neptunium–halide bonds have been prepared by salt metathesis and subsequent (pseudo)halide exchange reactions. Structural characterization in solid state (SC‐XRD) and in solution (NMR) showed the preservation of the chirality‐at‐metal throughout the series of heteroleptic fluoro, chloro, bromo, and azido complexes. More information can be found in the Communication by J. März et al. on page 8867.