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Cover Feature: A Lacunary Polyoxovanadate Precursor and Transition‐Metal‐Sandwiched Derivatives for Catalytic Oxidation of Sulfides (Chem. Eur. J. 40/2020)
Author(s) -
Wan Rong,
He Peipei,
Liu Zhen,
Ma Xinyi,
Ma Pengtao,
Singh Vikram,
Zhang Chao,
Niu Jingyang,
Wang Jingping
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202002867
Subject(s) - lacunary function , transition metal , catalysis , selectivity , reactivity (psychology) , chemistry , divalent , inorganic chemistry , topology (electrical circuits) , organic chemistry , mathematics , pure mathematics , combinatorics , medicine , alternative medicine , pathology
New topology of polyoxovanadates : A rare example of lacunary Keggin‐type vanadoselenite [SeV 10 O 28 (SeO 3 ) 3 ] 8− ({Se 4 V 10 }) was readily obtained, which shows sufficient reactivity with divalent transition metals (TMs) to form a new series of TM‐sandwiched complexes {(Se 4 V 10 ) 2 M} (M=Mn, Co, Zn). Such new TM‐derivatives can efficiently catalysis heterogeneous oxidation of sulfides in high conversion and selectivity under mild conditions. More information can be found in the Full Paper by J. Niu, J. Wang, et al. on page 8760.