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A New Class of C 2 ‐Symmetric Chiral Cyclopentadienyl Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application
Author(s) -
Liang Hao,
Vasamsetty Laxmaiah,
Li Teng,
Jiang Jijun,
Pang Xingying,
Wang Jun
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202001814
Subject(s) - cyclopentadienyl complex , ferrocene , rhodium , intramolecular force , iridium , ligand (biochemistry) , ruthenium , olefin fiber , chemistry , stereochemistry , catalysis , combinatorial chemistry , medicinal chemistry , organic chemistry , receptor , electrochemistry , biochemistry , electrode
A new class of C 2 ‐symmetric, chiral cyclopentadienyl ligand based on planar chiral ferrocene backbone was developed. A series of its corresponding rhodium(I), iridium(I), and ruthenium(II) complexes were prepared as well. In addition, the rhodium(I) complexes were evaluated in the asymmetric catalytic intramolecular amidoarylation of olefin‐tethered benzamides via C−H activation.