A New Class of  C  2 ‐Symmetric Chiral Cyclopentadienyl Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application | Zendy

Liang Hao | Zendy; Vasamsetty Laxmaiah | Zendy; Li Teng | Zendy; Jiang Jijun | Zendy; Pang Xingying | Zendy; Wang Jun | Zendy

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A New Class of C 2 ‐Symmetric Chiral Cyclopentadienyl Ligand Derived from Ferrocene Scaffold: Design, Synthesis and Application

Author(s) -

Liang Hao,

Vasamsetty Laxmaiah,

Li Teng,

Jiang Jijun,

Pang Xingying,

Wang Jun

Publication year - 2020

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202001814

Subject(s) - cyclopentadienyl complex , ferrocene , rhodium , intramolecular force , iridium , ligand (biochemistry) , ruthenium , olefin fiber , chemistry , stereochemistry , catalysis , combinatorial chemistry , medicinal chemistry , organic chemistry , receptor , electrochemistry , biochemistry , electrode

A new class of C 2 ‐symmetric, chiral cyclopentadienyl ligand based on planar chiral ferrocene backbone was developed. A series of its corresponding rhodium(I), iridium(I), and ruthenium(II) complexes were prepared as well. In addition, the rhodium(I) complexes were evaluated in the asymmetric catalytic intramolecular amidoarylation of olefin‐tethered benzamides via C−H activation.

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