Friedel–Crafts Type Methylation with Dimethylhalonium Salts | Zendy

Hämmerling Sebastian | Zendy; Voßnacker Patrick | Zendy; Steinhauer Simon | Zendy; Beckers Helmut | Zendy; Riedel Sebastian | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Friedel–Crafts Type Methylation with Dimethylhalonium Salts

Author(s) -

Hämmerling Sebastian,

Voßnacker Patrick,

Steinhauer Simon,

Beckers Helmut,

Riedel Sebastian

Publication year - 2020

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202001457

Subject(s) - friedel–crafts reaction , methylation , type (biology) , chemistry , organic chemistry , biology , biochemistry , paleontology , gene , catalysis

The dimethylchloronium salt [Me 2 Cl][Al(OTeF 5 ) 4 ] is used to methylate electron‐deficient aromatic systems in Friedel–Crafts type reactions as shown by the synthesis of N ‐methylated cations, such as [MeNC 5 F 5 ] + , [MeNC 5 F 4 I] + , and [MeN 3 C 3 F 3 ] + . To gain a better understanding of such fundamental Friedel–Crafts reactions, the role of the dimethylchloronium cation has been evaluated by quantum‐chemical calculations.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research