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Front Cover: Dirhodium(II)‐Catalyzed C(sp 2 )−H Azidation of Benzaldehydes (Chem. Eur. J. 30/2020)
Author(s) -
Wang Yi,
Fang Zaixiang,
Chen Xiaochuan,
Wang Yuanhua
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202001172
Subject(s) - azide , radical , chemistry , catalysis , cover (algebra) , front cover , polymer chemistry , photochemistry , organic chemistry , mechanical engineering , engineering
Taming azide radicals for catalytic C(sp2)−H azidation of benzaldehydes : In this manuscript, dirhodium complexes, represented by the classical Chinese lantern structure, reacted with azide radical to form Rh 2 (II,III) N 3 , which is responsible for the azide transfer. In the picture, the girl carrying a lantern illuminates the direction of the paper boats loading the azide radicals, which means the dirhodium complexes direct the free azide radical to the desired reaction pathway. More information can be found in the Full Paper by Y. H. Wang et al. on page 6805.