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Rhodium(III)‐Catalyzed C−H/N−H Functionalization with Hydrogen Evolution
Author(s) -
Xie Hui,
Jiang Jijun,
Wang Jun
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202000950
Subject(s) - rhodium , surface modification , catalysis , chemistry , hydrogen , hydrogen bond , medicinal chemistry , organic chemistry , molecule
A rhodium(III)‐catalyzed C−H/N−H bond functionalization of benzimidates with α‐chloroaldehydes to afford isoquinolin‐3‐ol derivatives is reported. No external oxidants are needed in this process, and interestingly, evolution of hydrogen gas is observed.

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