Front Cover: Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems (Chem. Eur. J. 27/2020) | Zendy

Hidalgo Nereida | Zendy; Moreno Juan José | Zendy; PérezJiménez Marina | Zendy; Maya Celia | Zendy; LópezSerrano Joaquín | Zendy; Campos Jesús | Zendy

Premium

Front Cover: Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems (Chem. Eur. J. 27/2020)

Author(s) -

Hidalgo Nereida,

Moreno Juan José,

PérezJiménez Marina,

Maya Celia,

LópezSerrano Joaquín,

Campos Jesús

Publication year - 2020

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202000841

Subject(s) - frustration , bimetallic strip , front cover , heterolysis , frustrated lewis pair , platinum , transition metal , cover (algebra) , chemistry , catalysis , lewis acids and bases , physics , condensed matter physics , engineering , organic chemistry , mechanical engineering

Introducing transition‐metal elements into frustrated Lewis pairs has emerged as a promising approach to develop new cooperative catalysts. Based on the heterolytic splitting of H 2 by Au I /Pt 0 combinations, this work reports the first system for which genuine bimetallic frustration has been demonstrated. This joint experimental/computational effort evinces the importance of balancing the degree of frustration versus M⋅⋅⋅M interaction to enhance small‐molecule activation. More information can be found in the Full Paper by J. López‐Serrano, J. Campos, et al. on page 5982.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research