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Docking Site Modulation of Isostructural Covalent Organic Frameworks for CO 2 Fixation
Author(s) -
Yang Fan,
Li Yusen,
Zhang Ting,
Zhao Ziqiang,
Xing Guolong,
Chen Long
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202000552
Subject(s) - isostructural , covalent bond , catalysis , chemistry , cycloaddition , fixation (population genetics) , combinatorial chemistry , organic chemistry , crystal structure , biochemistry , gene
Three isostructural covalent organic frameworks (COFs) with either methoxyl, hydroxyl, or both groups on the channel wall, are synthesized and served as metal‐free heterogeneous catalysts for chemical fixation of CO 2 . Among them, the COF decorated with both hydroxyl and methoxyl groups named OMe‐OH‐TPBP‐COF exhibits the highest catalytic activity and efficiency for CO 2 cycloaddition under mild conditions.
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