Premium
Optically Triggered Control of the Charge Carrier Density in Chemically Functionalized Graphene Field Effect Transistors
Author(s) -
Tang Zian,
George Antony,
Winter Andreas,
Kaiser David,
Neumann Christof,
Weimann Thomas,
Turchanin Andrey
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202000431
Subject(s) - azobenzene , materials science , graphene , field effect transistor , molecule , van der waals force , dipole , optoelectronics , nanotechnology , transistor , heterojunction , voltage , chemistry , polymer , physics , organic chemistry , composite material , quantum mechanics
Field effect transistors (FETs) based on 2D materials are of great interest for applications in ultrathin electronic and sensing devices. Here we demonstrate the possibility to add optical switchability to graphene FETs (GFET) by functionalizing the graphene channel with optically switchable azobenzene molecules. The azobenzene molecules were incorporated to the GFET channel by building a van der Waals heterostructure with a carbon nanomembrane (CNM), which is used as a molecular interposer to attach the azobenzene molecules. Under exposure with 365 nm and 455 nm light, azobenzene molecules transition between cis and trans molecular conformations, respectively, resulting in a switching of the molecular dipole moment. Thus, the effective electric field acting on the GFET channel is tuned by optical stimulation and the carrier density is modulated.