Long‐Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin–Calixarene Assemblies | Zendy

Gaeta Massimiliano | Zendy; Sortino Giuseppe | Zendy; Randazzo Rosalba | Zendy; Pisagatti Ilenia | Zendy; Notti Anna | Zendy; Fragalà Maria Elena | Zendy; Parisi Melchiorre F. | Zendy; D'Urso Alessandro | Zendy; Purrello Roberto | Zendy

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Long‐Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin–Calixarene Assemblies

Author(s) -

Gaeta Massimiliano,

Sortino Giuseppe,

Randazzo Rosalba,

Pisagatti Ilenia,

Notti Anna,

Fragalà Maria Elena,

Parisi Melchiorre F.,

D'Urso Alessandro,

Purrello Roberto

Publication year - 2020

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.202000126

Subject(s) - porphyrin , supramolecular chemistry , calixarene , supramolecular chirality , chirality (physics) , non covalent interactions , chemistry , aqueous solution , nanotechnology , materials science , combinatorial chemistry , photochemistry , molecule , organic chemistry , hydrogen bond , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark

The hierarchical assembly, in aqueous solution, of a new multi‐metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long‐range electronic communication.

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