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Long‐Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin–Calixarene Assemblies
Author(s) -
Gaeta Massimiliano,
Sortino Giuseppe,
Randazzo Rosalba,
Pisagatti Ilenia,
Notti Anna,
Fragalà Maria Elena,
Parisi Melchiorre F.,
D'Urso Alessandro,
Purrello Roberto
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.202000126
Subject(s) - porphyrin , supramolecular chemistry , calixarene , supramolecular chirality , chirality (physics) , non covalent interactions , chemistry , aqueous solution , nanotechnology , materials science , combinatorial chemistry , photochemistry , molecule , organic chemistry , hydrogen bond , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark
The hierarchical assembly, in aqueous solution, of a new multi‐metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long‐range electronic communication.