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Frontispiece: The Rise of Phosphaethynolate Chemistry in Early Transition Metals, Actinides, and Rare‐Earth Complexes
Author(s) -
Grant Lauren N.,
Mindiola Daniel J.
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201987161
Subject(s) - actinide , rare earth , chemistry , reagent , reactivity (psychology) , transition metal , inorganic chemistry , coordination complex , mineralogy , organic chemistry , metal , catalysis , medicine , alternative medicine , pathology
Phosphaethynolate or [OCP] − , the phosphorus analogue of cyanate , has become a valuable reagent extensively used as a P‐atom transfer source, as well as for the functionalization of other inorganic scaffolds. In this article, recent advances in the coordination chemistry and reactivity of [OCP] − with selected early transition metals, actinides, and rare‐earth complexes are discussed. For more information, see the Concept by Lauren N. Grant, and Daniel J. Mindiola on page 16171 ff.