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Frontispiece: Mechanisms and Beyond: Elucidation of Fluxional Dynamics by Exchange NMR Spectroscopy
Author(s) -
Nikitin Kirill,
O'Gara Ryan
Publication year - 2019
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201981863
Subject(s) - nuclear magnetic resonance spectroscopy , chemistry , spectroscopy , chemical physics , two dimensional nuclear magnetic resonance spectroscopy , molecular dynamics , molecule , computational chemistry , stereochemistry , organic chemistry , physics , quantum mechanics
Detailed mechanistic information is crucial to our understanding of reaction pathways and selectivity. Dynamic exchange NMR techniques, in particular 2D exchange spectroscopy (EXSY) and its modifications, provide indispensable intricate information on the mechanisms of organic and inorganic reactions and other phenomena, for example, the dynamics of interfacial processes. In the Review by K. Nikitin and R. O′Gara on page 4551 ff., key results from exchange NMR studies of small molecules over the last few decades are discussed.