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Bright Luminescent Platinum(II)‐Biaryl Emitters Synthesized Without Air‐Sensitive Reagents
Author(s) -
Wakasugi Chuei,
Yoshida Masaki,
Sameera W. M. C.,
Shigeta Yasuhiro,
Kobayashi Atsushi,
Kato Masako
Publication year - 2020
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201905821
Subject(s) - transmetalation , reagent , luminescence , platinum , chemistry , surface modification , combinatorial chemistry , photochemistry , materials science , organic chemistry , optoelectronics , catalysis
Transition‐metal complexes bearing biaryl‐2,2′‐diyl ligands tend to show intense luminescence. However, difficulties in synthesis have prevented their further functionalization and practical applications. Herein, a series of platinum(II) complexes bearing biaryl‐2,2′‐diyl ligands, which have never been prepared in air, were synthesized through transmetalation and successive cyclometalation of biarylboronic acids. This approach does not require any air‐ or moisture‐sensitive reagents and features a simple synthesis even in air. The resulting (Et 4 N) 2 [Pt( m , n ‐F 2 bph)(CN) 2 ] ( m , n ‐F 2 bph= m , n ‐difluorobiphenyl‐2,2′‐diyl) complexes exhibit intense green emissions with high quantum efficiencies of up to 0.80 at 298 K. The emission spectral fitting and variable‐temperature emission lifetime measurements indicate that the high quantum efficiency was achieved because of the tight packing structure and strong σ‐donating ability of bph.