Luminescence‐Driven Electronic Structure Determination in a Textbook Dimeric Dy III ‐Based Single‐Molecule Magnet | Zendy

Guettas Djamila | Zendy; Gendron Frédéric | Zendy; Fernandez Garcia Guglielmo | Zendy; Riobé François | Zendy; Roisnel Thierry | Zendy; Maury Olivier | Zendy; Pilet Guillaume | Zendy; Cador Olivier | Zendy; Le Guennic Boris | Zendy

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Luminescence‐Driven Electronic Structure Determination in a Textbook Dimeric Dy III ‐Based Single‐Molecule Magnet

Author(s) -

Guettas Djamila,

Gendron Frédéric,

Fernandez Garcia Guglielmo,

Riobé François,

Roisnel Thierry,

Maury Olivier,

Pilet Guillaume,

Cador Olivier,

Le Guennic Boris

Publication year - 2020

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201905493

Subject(s) - dysprosium , acetylacetone , luminescence , lanthanide , magnet , magnetism , crystallography , single molecule magnet , molecule , chemistry , materials science , inorganic chemistry , magnetic field , ion , condensed matter physics , physics , optoelectronics , magnetization , organic chemistry , quantum mechanics

A textbook dysprosium dinuclear complex based on acetylacetone ligands, [Dy 2 (acac) 4 (μ 2 ‐acac) 2 (H 2 O) 2 ], has been synthesized and fully characterized. This simple dimeric lanthanide complex shows well‐resolved solid‐state luminescence and behaves as a single‐molecule magnet under zero DC field. A seminal crystal‐field approach is used to marry both magnetism and luminescence in the frame of an energetic picture.

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